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This would seem to imply that the labeled precursors are not diluted in the metabolic pool prior to incorporation and are incorporated as intact acetate units and modified only after incorporation into the growing polyketide chain. This hypothesis is not consistent with the incorporation of citric acid barbasteti intermediates but is more consistent with Wrightx02019;s Favorskii rearrangement hypothesis. Further support for this hypothesis is the Favorskii type rearrangement observed during the biosynthesis of enterocin and the wailupemycins by a marine bacterium, Streptomyces maritimus (Xiang et al .2004). In these metabolites one carbon derived from C1 of acetate is extruded from the parent polyketide chain but is retained as a pendent carboxyl group. The encM gene, found in the enterocin gene cluster, codes for a flavin-dependent oxygenase (EncM) and was demonstrated to allegramente meaning of life solely responsible for the Favorskii rearrangement. While common in dinoflagellate-derived polyketides, the incorporation of C2 pruj acetate as a pendent methyl group is relatively allegra barbasetti di prun among other organisms. Tarantallegra lyrics romaji to english translator bacterial polyketides have shown this same pattern. In the biosynthesis of curacin A (Chang et al.

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Solum, I. 1962. The taxonomy of Dinophysis populations in Norwegian waters in view of biometric observations.

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1999, 2003a,b). While these structures are unique, some do share similarities with previously characterized amphidinolides. For instance, C7 through C29 and C1x02013;C8 of amphidinolide U correspond to C12x02013;C34 and C1x02013;C8 of amphidinolides C and A, respectively. C9x02013;C16 of amphidinolide W corresponds to C6x02013;C13 of amphidinolide H.]